贵州汇善谷锶-偏硅酸复合型天然饮用矿泉水成因探讨Discussion on Strontium-Metasilicic Acid CompositeType Natural Drinking Mineral Water Genesis in Huishangu,Guizhou
罗腾,陈正山,王甘露,牟雨亮,李超,毛铁
摘要(Abstract):
绥阳汇善谷温泉是贵州省内碳酸盐岩分布区十分少有的锶-偏硅酸复合型天然温矿泉水。通过对研究区水文地质条件、温矿泉水的水文地球化学及环境同位素特征分析,认为汇善谷复合型温矿泉水的形成受水-岩作用和构造作用控制。温矿泉水中δ~(87)Sr/~(86)Sr同位素值0.709 1~0.709 2,指示锶元素来源于碳酸盐岩-蒸发盐岩建造中的含锶矿物,未见幔源锶供给。δD-~(18)O、δ~(34)SO_4~(2-)同位素表明,该温泉矿泉水在区域内接受大气降水后沿构造面向地下深部渗透循环增温,形成较高温度的地热水,并在CO_2参与下与娄山关组天青石(SrSO_4)和蒸发岩(CaSO_4)及类质同象于石膏、文石、方解石等矿物发生水-岩作用形成富Sr-SO_4~(2-)·HCO_3~--Ca·Mg型水。H_2SiO_3形成在热储深度2 172.8~2 811.2m,热储温度68.9~85.4℃的地质条件下石英矿物的水解和地热水沿断裂对流循环过程中溶滤先期形成的硅化碳酸盐岩、石英脉矿物,使SiO_2不断迁移、富集并结合水体中H+形成H_2SiO_3型温矿泉水。
关键词(KeyWords): 环境同位素;水-岩作用;复合型温矿泉水;贵州汇善谷
基金项目(Foundation): 贵州省地勘基金项目“贵州省理疗温泉(地热井)调查评价”(2017-02)
作者(Author): 罗腾,陈正山,王甘露,牟雨亮,李超,毛铁
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