任辉,周锋,宁树正,王松,兰友根

• 1:中国煤炭地质总局
• 2:中能冰气能源科技(北京)有限公司

摘要(Abstract)：

可燃冰(天然气水合物)是分布于深海沉积物或陆域的永久冻土中,由天然气与水在高压低温条件下形成的类冰状的结晶物质。人工可燃冰是在一定温度和压力条件下,在动力学添加剂和热力学添加剂的作用下,将天然气中的甲烷分子与游离水混合后,人工结合形成的结晶笼状固体。人工可燃冰因其压缩比例大、储存环境简便、运输环节没有爆炸危险等安全隐患,在天然气储运领域具有独特的应用前景。同时,因不同气体形成水合物条件差异大等特点,人工可燃冰技术具有天然的提纯作用,尤其是在煤矿低浓度瓦斯提纯方面具有独特的应用前景。

关键词(KeyWords)： 可燃冰;人工可燃冰;开发利用;天然气储运;低浓度瓦斯提纯

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 任辉,周锋,宁树正,王松,兰友根

参考文献(References)：

• [1]John J Carroll,杜建芬.天然气各组分形成水合物关联式[J].天然气工业,2002,22(2):66-70.
• [2]Arthur D Pelton.Fact Database Development Consortium Project:second year progress report(1 October 2001 to 30 September 2002,A-bridged)[R].Canada:Ecole Polytechnique de Montreal,2001.
• [3]Khaled Ahmed Abdel fattah.Evaluation of Empirical Correlations for Natural Gas Hydrate Predictions[J].Oil and Gas Business,2004,55(9):467-472.
• [4]Sloan E D.Natural Gas Hydrates[J].Journal of Petroleum Technology,1991:1414-1417.
• [5]John Carroll.Natural Gas Hydrates:A Guide for Engineers[M].New York:Gulf Professional Co,2003.
• [6]Sloan E D.Clathrates Hydrates of Natural Gas(2nd Edtion)[M].New York:Marcel Dekker Inc,1998.
• [7]Marit Mork.Formation Rate of Natural Gas Hydrate-Reactor Experiments and Models[D].Trondhein Norway:Norwegian University of Science and Technology,2002.
• [8]Jeon Y H,Kim N J,Chun W G,Lim S H,Kim C B,Hur B K.Astudy of the kinetics characteristics of natural gas hydrate[J].Journal of Industrial and Engineering Chemistry,2006,12(5):733-738.
• [9]Gudmundsson J S,Parlaktuna M,Khokhar A A.Storage of Natural Gas as Frozen Hydrate[J].SPE Production and Facilities,1994,9(1):69-73.
• [10]Gudmundsson J S,Borrehaug A.Frozen Hydrate for Transport of Natural Gas[C]//Proceeding of the 2nd International Conference on Natural Gas Hydrates.Toulouse:CEDEX.1996:415-422.
• [11]Mork M,Gudmundsson J S.Hydrate formation rate in a continuous stirred tank reactor,experimental results and bubble-to-crystal model[C]//Proceedings of the Fourth International Conference on Gas Hydrate,Yokohama,Japan,2002.
• [12]Gudmundsson J S,Mork M,Graff O F.Hydrate non-pipeline technology[C]//Proceedings of the Fourth International Conference on Gas Hydrate.Yokohama,Japan,2002.
• [13]Mork M,Gudmundsson J S.Rate of hydrate formation,experimental results and empirical correlation[C]//13th International Oil Field Chemistry Symposium.Geilo,Norway,2002.
• [14]Mork M,Gudmundsson J S,Parlaktuna M.Hydrate formation rate in a continuous stirred tank reactor[C]//2001 International Conference on Gas Research.Amsterdam,the Netherlands,2001.
• [15]Gudmundsson J S,Mork M.Stranded gas to hydrate for storage and transport[C]//2001 International Conference on Gas Research.Amsterdam,the Netherlands,2001.
• [16]Mork M,Gudmundsson J S.Rate of hydrate formation in subsea pipelines,correlation based on reactor experiments[C]//13th International Oil Field Chemistry Symposium.Geilo,Norway,2001.
• [17]Gudmundsson J S,Andersson V,Levik O I,Mork M.Hydrate technology for capturing stranded gas[J].Annals of New York Academy of Science,2006,912(1):403-410.
• [18]Gudmundsson J S,Andersson V,Durgut I,Levik O I,Mork M.NGH on FPSO slurry process and cost estimate[C]//SPE Annual Technical Conference and Exhibition.SPE paper 56629,Houston,USA,1999.
• [19]Gudmundsson J S.Method for Production of Gas Hydrate for Transportation and Storage[P].US:Patent,5536893,1996-07-16.
• [20]Timothy S Collett.Energy resource potential of natural gas hydrates[J].AAPG Bulletin,2002,86(11):1971-1992.
• [21]Atanas Vassilev,Lyobomir Dimitrov.Bulgarian National Program for Gas Hydrates Reseach[J].Geology and Geophysics,2013,46:425-430.
• [22]Ryo Ohmura,Toru Shigetomi,Yasuhiko H Mori.Formation,growth and dissociation of clathrate hydrate crystals in liquid water in contact with a hydrophobic hydrate-forming liquid[J].Journal of Crystal Growth,1999,196(1):164-173.
• [23]罗承先.NKK开发成功天然气水合物生产技术[J].中国石化,2003(3):94-94.
• [24]金翔龙,戴金星,马在田,欧阳自远,秦蕴珊,汪品先,王先彬,周蒂,朱伟林,赵生才.关于开展中国天然气水合物研究的建议[J].地球科学进展,2002,17(3):465-466.
• [25]张文玲,李海国,王胜杰,刘芙蓉.水合物储运天然气技术的研究进展[J].天然气工业,2000,20(3):95-97.
• [26]舒碧芬,郭开华,张奕.气体水合物生成过程的特性研究[C]//中国工程热物理传热传质学术会议论文集.江西庐山,1996:79-83.
• [27]张世喜,陈光进,郭天民.利用气体水合物技术分离含氢气体混合物[J].中国石油大学学报:自然科学版,2004,28(1):95-97.
• [28]张世喜,陈光进,杨兰英,等.含氢气体水合物生成条件的测定和计算[J].化工学报,2003,54(01):24-28.
• [29]郑军卫,史斗.从文献计量角度看从文献计量角度看国际天然气水合物研发态势[J].天然气地球科学,2005,16(6):825-929.
• [30]樊栓狮等.天然气水合物储存与运输技术[M].北京:化学工业出版社,2005.
• [31]陈光进.气体水合物科学与技术[M].北京:化学工业出版社,2008.