中低煤阶镜质组微孔结构对甲烷吸附能力的影响Impact from Medium to Low Ranked Coal Vitrinite Micropore Structure on Methane Adsorptivity
丁立奇,赵萌,魏迎春,王安民
摘要(Abstract):
为探究中低煤阶镜质组微孔结构对甲烷吸附能力的影响,选取8个不同变质程度的镜煤煤样,通过CO_2吸附实验对煤样微孔(小于2 nm)结构进行表征,并对煤样进行了甲烷等温吸附试验。实验结果表明:煤样微孔比表面积与微孔体积随着R_o的变化基本一致,呈现高—低—高的变化趋势,当R_o在0.46%~1.46%时,比表面积、孔体积随着变质程度的增高而减少,而R_o在1.46%~2.15%时,比表面积、孔体积随着变质程度的增高而增加。煤样兰氏体积随R_o的变化呈现三段式变化,当R_o在0.46%~0.82%时,兰氏体积随着变质程度的提高而增加;当R_o在0.82%~1.52%时,兰氏体积随着变质程度的提高而减少;当R_o在1.52%~2.15%时,兰氏体积随着变质程度的提高而增加。兰氏体积随着微孔体积的增加呈波动式变化,但整体呈减少的趋势。
关键词(KeyWords): 煤变质程度;镜质组;微孔结构;兰氏体积
基金项目(Foundation): 国家自然科学基金(41902170,41972174,42072197)
作者(Author): 丁立奇,赵萌,魏迎春,王安民
参考文献(References):
- [1]傅雪海,秦勇,张万红,等.基于煤层气运移的煤孔隙分形分类及自然分类研究[J].科学通报,2005(S1):51-55.
- [2]Chikatamarla L and Peter J C.Role of coal type and rank on methane sorption characteristics of Bowen Basin,Australia coals[J].International Journal of Coal Geology,1999,40(4):309-325.
- [3]Li X C,Chen X L,Zhang F,et al.Energy Calculation and Simulation of Methane Adsorbed by Coal with Different Metamorphic Grades.[J].ACS omega,2020,5(25) :14976-14989.
- [4]苏现波,张丽萍,林晓英.煤阶对煤的吸附能力的影响[J].天然气工业,2005(1):19-21+205-206.
- [5]姚艳斌,刘大锰.华北重点矿区煤储层吸附特征及其影响因素[J].中国矿业大学学报,2007(3):308-314.
- [6]Zhao X,Feng T,Wang P,et al.Study on the Effect of Soft and Hard Coal Pore Structure on Gas Adsorption Characteristics[J].Advances in Civil Engineering,2021(1):1-10.
- [7]Zhang M,Duan C C,Li G F,et al.Determinations of the multifractal characteristicsof the pore structures of low-,middle-,and high-rank coal using high-pressure mercury injection[J].Journal of Petroleum Science and Engineering,2021(203).
- [8]赵兴龙,汤达祯,许浩,等.煤变质作用对煤储层孔隙系统发育的影响[J].煤炭学报,2010,35(9):1506-1511.
- [9]马东民,高正,陈跃,等.不同温度下低、中、高阶煤储层甲烷吸附解吸特征差异[J].油气藏评价与开发,2020,10(4):17-24+38.
- [10]刘彦伟,张鑫淼,苗健.中高阶煤孔隙结构的演化规律研究[J].煤矿安全,2020,51(11):7-13.
- [11]Cai Y,Liu D M,Pan Z J,et al.Pore structure and its impact on CH4 adsorption capacity and flow capability of bituminous and subbituminous coals from Northeast China[J].Fuel,2013(103):258-268.
- [12]Xu S P,Hu E F,Li X C,et al.Quantitative analysis of pore structure and its impact on methane adsorption capacity of coal[J].Natural Resources Research,2020,30(1):605-620.
- [13]IUPAC.Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity[J].Pure and Applied Chemistry,1982,54(11):2201-2218.
- [14]陈跃,汤达祯,田霖,等.煤变质程度对中低阶煤储层孔裂隙发育的控制作用[J].天然气地球科学,2017,28(4):611-621.
- [15]聂敬,李勇,魏迎春,等.鄂尔多斯盆地北缘石炭-二叠纪/侏罗纪煤储层特征对比分析[J].中国煤炭地质,2017,29(11):13-16.
- [16]钟玲文.煤的吸附性能及影响因素[J].地球科学,2004(3):327-332+368.
- [17]穆福元,王红岩,吴京桐,等.中国煤层气开发实践与建议[J].天然气工业,2018,38(9):55-60.
- [18]钟玲文,张慧,员争荣,等.煤的比表面积孔体积及其对煤吸附能力的影响[J].煤田地质与勘探,2002(3):26-29.
- [19]Pei L,Ma D M,Zhang J C,et al.Wettability modification and its influence on methane adsorption/desorption:A case study in the Ordos Basin,China[J].Energy Science & Engineering,2020,8(3):804-816.
- [20]Dubinin M M.The potential theory of adsorption of gases and vapors foradsorbents with energetically nonuniform surfaces[J].Chemical Reviews,1960(60).
- [21]Astakhov V A,Dubinin M M.Development of the concept of volume filling of micropores in the adsorption of gases and vapors by microporous adsorbents[J].Bulletin of the Academy of Sciences of the Ussr Division of Chemical Science,1971,20(1):13-16.
- [22]陈鹏.中国煤炭性质、分类和利用[M].北京:化学工业出版社,2001:81-83.
- [23]段旭琴,曲剑午,王祖讷.低变质烟煤有机显微煤岩组分的孔结构分析[J].中国矿业大学学报,2009,38(2):224-228.
- [24]魏迎春,项歆璇,王安民,等.不同矿化度水对煤储层吸附性能的影响[J].煤炭学报,2019,44(9):2833-2839.
- [25]王安民,曹代勇,聂敬,等.巨厚煤储层孔隙结构的垂向非均质性特征——以青海聚乎更矿区为例[J].石油学报,2020,41(6):691-701.
- [26]王安民.青海聚乎更矿区煤系气耦合成藏条件研究[D].北京:中国矿业大学(北京),2018.
- [27]王安民,曹代勇,魏迎春.煤层气选区评价方法探讨——以准噶尔盆地南缘为例[J].煤炭学报,2017,42(4):950-958.
- [28]魏迎春,崔茂林,张劲,等.煤层气开发中不同粒度煤粉的聚集沉降实验[J].煤田地质与勘探,2020,48(5):40-47.
- [29]魏迎春,贾煦,刘志飞,等.鸳鸯湖矿区延安组煤岩煤质特征及成煤环境研究[J]].煤炭科学技术,2018,46(7):197-204+196.