基于HRTEM新景矿无烟煤的化学结构特征研究Study on Anthracite Chemical Constitution Features through HRTEM in Xinjing Coalmine
华思维,杨文斌,闫金超,舒家兴,孙澳,李伍
摘要(Abstract):
为充分了解煤微观结构,利用高分辨率透射电镜(HRTEM)观察新景矿无烟煤,在不同温度的电镜图像下观察煤样形貌,使用PS及插件处理透射电镜原始照片并进行一系列定量表征,得到煤样芳香片层的条纹长度及定向性,以及曲率、累计角度等一系列参数。选取无烟煤在不同温度下10 nm的照片,分析了无烟煤结构特征,为进一步了解煤微观结构提供一定的理论依据。研究结果表明,该煤样的晶格条纹集中分布在2×2和3×3并以2×2为主;煤样在300~600℃主要呈低环数的芳香层片,随着温度升高,条纹方向逐渐呈现一致性;该煤样为高煤级无烟煤,取向性较好,整体呈现一致的演化规律,且随着温度升高,煤变质作用增强,煤结构逐渐向有序性演化。
关键词(KeyWords): 晶格条纹;定向性;曲率;累计角度
基金项目(Foundation): 国家自然科学基金面上项目(41972169);; 中国矿业大学大学生创新训练资助项目(202010290197H)
作者(Author): 华思维,杨文斌,闫金超,舒家兴,孙澳,李伍
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