生烃热模拟研究进展及对非常规油气成藏研究约束Hydrocarbon Generation Thermal Simulation Research Progress and Constraint on Unconventional Oil and Gas Reservoiring Study
栾治盛,杜江峰,孙平昌,侯丽云,丁聪
摘要(Abstract):
生烃热模拟实验是烃源岩成烃潜力与资源评价的重要手段,也是揭示页岩油气等非常规能源成藏序列的重要正演方法。生烃热模拟实验可以根据体系的开放性分为开放体系、封闭体系和半开放体系热模拟实验,选择不同的模拟实验方法应用于不同的研究目的。开放体系是与干酪根初始裂解反应最相近的热模拟方法,半开放体系是最为接近实际地质体中烃源岩热演化的热模拟体系,封闭体系更适用于Ⅲ型干酪根生烃模拟的研究,是认识重烃二次裂解的重要方法。在有机质热演化过程中,生成油气会受温度、压力、水介质、催化剂等条件的影响,这些外界因素也会对热模拟实验产生重要影响。热模拟实验在非常规资源中应用较广泛,既可以研究烃源岩的生排烃特征、成烃潜力及油气滞留特征;也可以分析作为储层的泥页岩的储集物性及孔隙类型演化特征等。目前热模拟实验在碳酸盐岩烃源岩热模拟实验、页岩热演化过程中的微米-纳米孔隙结构变化特征,有机质生排烃与泥页岩储集物性的协同演化关系这三个方面取得重要进展,也是未来的主攻方向。
关键词(KeyWords): 热模拟;有机质;储层;非常规油气;发展方向
基金项目(Foundation): 国家自然科学基金项目“松辽盆地上白垩统青山口组有机质旋回的天文年代信息示踪及有机质富集定量模型建立”(41402088);国家自然科学基金项目“油页岩纹层中古环境信息重建及毫米级有机质富集机理研究”(41772092)和松辽盆地基底古生界油气潜力评价(DD20211341)
作者(Author): 栾治盛,杜江峰,孙平昌,侯丽云,丁聪
参考文献(References):
- [1]肖芝华,胡国艺,李志生.从烃源岩热模拟实验讨论其生烃特征[J].天然气地球科学,2008(4):544-547.
- [2]汤庆艳,张铭杰,张同伟,等.生烃热模拟实验方法述评[J].西南石油大学学报(自然科学版),2013,35(1):52-62.
- [3]彭威龙,胡国艺,刘全有,等.热模拟实验研究现状及值得关注的几个问题[J].天然气地球学,2018,29(9):1252-1263.
- [4]Connan J.Time-temperatu re relation in oil genesis[J].AAPG Bulletin ,1974(58):2516-2521.
- [5]Hunt J.PetroleumGeochemistry and Geology[M].Mew York:W H Freeman and Company,1979:67-178.
- [6]Waples D.Time and temperature in petroleum formation:application of Lopatin's method to petroleum exploration[J].AAPG Bulletin,1980,64(7):916-926.
- [7]Tissot B P,Welte D H.Pertroleum Formation and Occurrence [M].Second ed.Berlin,Heidelberg,New York:Springer-Verlag,1984:74-266.
- [8]姜峰,张友联,杜建国.油气生成热模拟实验研究进展[J].地球科学进展,1996,11(5).
- [9]王民,卢双舫,王东良,等.不同热模拟实验煤热解产物特征及动力学分析[J].石油学报,2011,32(5):806-814.
- [10]吉利明,吴远东,贺聪,等.富有机质泥页岩高压生烃模拟与孔隙演化特征[J].石油学报,2016,37(2):172-181.
- [11]Tang Y,Behar F.Rate Constants of n-Alkanes Generation from Type II Kerogen in Open and Closed Pyrolysis Systems[J].Energy & Fuels,1995,9(3):507-512.
- [12]Schenk H J,Dieckmann V.Prediction of petroleum formation:the influence of laboratory heating rates on kinetic parameters and geological extrapolations[J].Marine & Petroleum Geology,2004,21(1):79-95.
- [13]Niu C K,Jiang F J,Li Y X,et al.Organic geochemical character-istics and hydrocarbon generation simulationof shallow sediments in Shao-bo Lake,Eastern China[J].SEG interpretation,2019,7(2):293-308.
- [14]Mohamed Elfatih Z Gandol.Hydrocarbon Generation Simulation of Abu Gabra Formation in Northern Muglad Basin,Sudan[J].Journal of Petroleum and Mining Engineering,2020,3(6).
- [15]高岗.油气生成模拟方法及其石油地质意义[J].天然气地球科学,2000,11(2):25-29.
- [16]邹艳荣,帅燕华,孔枫,等.油气生成过程实验研究的思考与展望[J].石油实验地质,2004(4):375-382.
- [17]李贤庆,周强,汪为孝,等.库车坳陷三叠—侏罗纪烃源岩生气特征与生气模式[J].煤田地质与勘探,2007,35(6):18-22.
- [18]鲍园.生物成因煤层气定量判识及其成藏效应研究[D].江苏徐州:中国矿业大学,2013.
- [19]张文正,杨华,李剑锋,等.论鄂尔多斯盆地长_7段优质油源岩在低渗透油气成藏富集中的主导作用——强生排烃特征及机理分析[J].石油勘探与开发,2006(3):289-293.
- [20]吴远东,张中宁,吉利明,等.高压生烃模拟实验及其成油滞后特征[J].特种油气藏,2016,23(3):129-132+157.
- [21]王强,彭平安,张文正,等.鄂尔多斯盆地延长组7段页岩全组分定量生烃模拟及原油可动性评价[J].石油学报,2018,39(5):541-553.
- [22]张建坤,何生,易积正,等.岩石热声发射和盆模技术研究中扬子区西部下古生界海相页岩最高古地温和热成熟史[J].石油学报,2014,35(1):58-67.
- [23]林拓,张金川,李博,等.湘西北常页1井下寒武统牛蹄塘组页岩气聚集条件及含气特征[J].石油学报,2014,35(5):839-846.
- [24]Ma Z L,Zheng L J,Xu X H,et al.Thermal simulation experiment of organic matter-rich shale and implication for organic pore formation and evolution[J].Petroleum Research,2017,2(4).
- [25]Cui H Y,Liang F,Ma C,et al.Pore evolution characteristics of Chinese marine shale in the thermal simulation experiment and the enlightenment for gas shale evaluation in South China[J].Geosciences Journal,2019,23(4).
- [26]董春梅,马存飞,栾国强,等.泥页岩热模拟实验及成岩演化模式[J].沉积学报,2015,33(5):1053-1061.
- [27]谭静强,张煜麟,罗文彬,等.富有机质泥页岩微纳米孔隙结构研究进展[J].矿物岩石地球化学通报,2019,38(1):18-29+203.
- [28]宋董军,吴陈君,陈科,等.海陆相泥页岩气体生成的半封闭模拟实验[J].地球科学,2019,44(11):3639-3652.
- [29]李楚雄,申宝剑,潘安阳,等.波罗的海盆地上奥陶统页岩孔隙演化的热压模拟实验[J].石油实验地质,2020,42(3):434-442.
- [30]侯读杰.热模拟实验技术简介[J].国外地质勘探技术,1990(10):39-40.
- [31]Eisma E ,Jurg J W.Fundamental aspects of the diagenesis of organic matter and the formation of hydrocarbons[C] // Proceedings of 7th world Petroleum Congress.London:Applied Sciece Pub,1967(2):61-72.
- [32]Henderson W,Eglinton G,Simmods P,et al.Thermal alteration as a contributory process to the genesis of petroleum[J].Nature,1968,219(5158):1012-1016.
- [33]Brooks J D,Smith J W.The diagenesis of plant lipids during the form ation of coal,petroleum and natural gas;Ⅱ,Coalification and th e formation of oil and gas in the Gippsland Basin [J].Geochimicaet Cosmochmica Acta,1969,33(10):1183-1194.
- [34]Tissot B P,Welte D H.Petroleum Formation and Occurrence:a New Appoach to Oiland Gas Exploration[ M].Berlin-Heidebery-New York:Springer-Verlag,1978.
- [35]Dembicik H.The effects of the mineral matrix on the determination of kinetic parameters using modified Rock Eval pyrolysis[J].Pergamon,1992,18(4).
- [36]Schouten S,De G W,Sinninghe D J S,et al.Laboratory simulation of natural sulphurization:II.Reaction of multi-functionalized lipids with inorganic polysulphides at low temperatures[J].Pergamon,1994,22(3-5).
- [37]徐振泰,左顺林.干酪根向油、气演化的热变模拟试验[J].石油学报,1981(S1):25-31.
- [38]刘德汉.煤成气和煤成油产出阶段和特征的初步研究[M] // 中国科学院地球化学研究所年报.贵阳:贵州人民出版社,1986:185-196.
- [39]张惠之.不同煤岩组分的热解成气实验研究[M] // 中国科学院地球化学研究所年报.贵阳:贵州人民出版社,1986:150-152.
- [40]Lewan M D,Winters J C,Mcdonald J H.Generation of oil-like pyrolyzates from organic-rich shales[J].Science,1979(203):897-899.
- [41]Behar F,Kressmann S,Rudkiewica J L,et al.Experimental simulation in a confined system and kinetic modelling of kerogen and oil cracking[J].Pergamon,1992,19(1-3).
- [42]Lewan M D.Laboratory simulation of petroleum formation[M].New York:Org Geochem Plenum Publishing,1993.
- [43]Pan C C,Jiang L,Liu J Z,et al.The effects of calcite and montmorillonite on oil cracking in confined pyrolysis experiments[J].Organic Geochemistry,2010,41(7).
- [44]贾望鲁,帅艳华,彭平安,等.塔北轮南地区原油沥青质生烃动力学研究[J].科学通报,2004(S1):76-80.
- [45]张闯辉.煤中镜质组生烃演化的热模拟实验研究[D].江苏徐州:中国矿业大学,2018.
- [46]Berner U,Faber E.Empirical carbon isotope/maturity relationships for gases from algal kerogens and terrigenous organic matter,based on dry,open-system pyrolysis[J].Organic Geochemistry,1996,24(10):947-955.
- [47]Cramer B.Methane generation from coal during open system pyrolysis investigated byisotope specific,Gaussian distributed reaction kinetics[J].Organic Geochemistry,2004,35(4):379-392.
- [48]Liu Q,Liu W,Dai J.Characterization of pyrolysates from maceral components of Tarim coals in closed system experiments and implications to natural gas generation[J].Organic Geochemistry,2007,38(6):921-934.
- [49]Koji U.Takahashi,Noriyuki S.Semi-open and closed system pyrolysis of Paleogene coal for evaluating the timing of hydrocarbon gas expulsion[J].International Journal of Coal Geology,2017(178).
- [50]卢双舫,王民,王跃文,等.密闭体系与开放体系模拟实验结果的比较研究及其意义[J].沉积学报,2006,24(2):282-288.
- [51]米敬奎,戴金星,张水昌,等.煤在2种不同体系的生气能力研究[J].天然气地球科学,2007(2):245-248+274.
- [52]He K,Zhang S C,Mi J K,et al.The speciation of aqueous sulfate and its implication on the initiation mechanisms of TSR at different temperatures[J].Applied Geochemistry,2014(43).
- [53]张毅,胡守志,廖泽文,等.基于压机热模拟实验的页岩孔隙演化特征[J].地球科学,2019,44(3):983-992.
- [54]Tang Y,Perry J K,Jendan P D,et al.Mathematical modeling of stable carbon isotope ratios in natural gases[J].Geochim.Cosmochim.Acta,2000,64(15).
- [55]Chen J Q,Zhang X G,Chen Z H,et al.Hydrocarbon expulsion evaluation based on pyrolysis Rock-Eval data:Implications for Ordovician carbonates exploration in the Tabei Uplift,Tarim[J].Journal of Petroleum Science and Engineering,2021(196).
- [56]高喜龙,肖贤明,刘中云,等.用开放体系的热解方法对烃源岩生烃动力学的研究:以东营凹陷某生油岩为例[J].地球化学,2003(5):485-490.
- [57]米敬奎,张水昌,王晓梅.不同类型生烃模拟实验方法对比与关键技术[J].石油实验地质,2009,31(4):409-414.
- [58]胡俊,程峰,刘祥春,等.Py-GC-MS分析神华煤热解产物煤焦油组成[J].天然气化工(C1化学与化工),2020,45(4):94-96+116.
- [59]于丰宁.常压快速升温过程中油页岩有机质演化及生烃特征[D].长春:吉林大学,2020.
- [60]马丽.依兰第三煤矿煤的生烃热演化实验研究[D].北京:中国矿业大学,2017.
- [61]王义凤,王东良,李志生,等.“MSSV”油气生成模拟实验技术[J].现代科学仪器,2009(4):115-117.
- [62]王云鹏,耿安松,刘德汉,等.页岩、煤、沥青和原油的生气实验研究[J].沉积学报,2004(S1):106-109+117.Wang Y P,Geng A S,Liu D H,et al .Comparison of Experimental Results between Two Simulation Methods[J].Acta Sedimentologica Sinica,2004(S1):106-109+117.
- [63]Hall P A,Watson A F R,Garner G V,et al.Horsfield.An investigation of micro-scale sealed vessel thermal extraction-gas chromatography-mass spectrometry (MSSV-GC-MS#) and micro-scale sealed vessel pyrolysis-gas chromatography-mass spectrometry applied to a standard reference material of an urban dust/organics[J].Science of the total Environment,1999,235(1-3):269-276.
- [64]Mi J K,Zhang S C,Su J,et al.The upper thermal maturity limit of primary gas generated from marine organic matters[J].Elsevier Ltd,2018(89).
- [65]Song D J,Tuo J C,Zhang M F,et al.Hydrocarbon Generation Potential and Evolution of Pore Characteristics of Mesoproterozoic Shales in North China:Results from Semi-Closed Pyrolysis Experiments[J].Journal of Natural Gas Science and Engineering,2018.
- [66]王治朝,米敬奎,李贤庆,等.生烃模拟实验方法现状与存在问题[J].天然气地球科学,2009,20(4):592-597.
- [67]赵晗,马中良,郑伦举,等.有限空间温压共控热模拟油气产物地球化学特征[J].天然气地球科学,2020,31(1):73-83.
- [68]傅飘儿,李晓亚,汤庆艳,等.珠江口盆地番禺低隆起—白云凹陷北坡干酪根热演化模拟与生烃[J].沉积学报,2013,31(1):176-183.
- [69]Mi J K,Zhang S C,He K.Experimental investigations about the effect of pressure on gas generation from coal[J].Elsevier Ltd,2014(74).
- [70]赵岩.火山物质特征化合物对烃源岩生烃演化的影响[D].西安:西北大学,2018.
- [71]彭威龙,刘全有,胡国艺,等.天然气形成过程中碳同位素分馏机理——来自热模拟实验的地球化学证据[J].石油勘探与开发,2020,47(5):972-983.
- [72]董鹏,李贤庆,仰云峰,等.原油裂解成气动力学研究进展[J].矿物岩石地球化学通报,2009,28(2):201-208.
- [73]董泽亮,李贤庆,杨杰,等.煤系烃源岩生气热模拟实验研究[J].中国煤炭地质,2015,27(6):12-17+34.
- [74]陶伟,邹艳荣,刘金钟,等.压力对黏土矿物催化生烃的影响[J].天然气地球科学,2008(4):548-552+570.
- [75]Zou Y R,Peng P A.Overpressure retardation of organic-matter maturation:a kinetic model and its application[J].Marine and Petroleum Geology,2001,18(6).
- [76]包友书,张林晔,张守春,等.烃源岩生烃抑制模拟实验及机理[J].石油学报,2017,38(7):753-762.
- [77]刘文汇,王万春.烃类的有机(生物)与无机(非生物)来源-油气成因理论思考之二[J].矿物岩石地球化学通报,2000,19(3):179-186.
- [78]王晓锋,刘文汇,徐永昌,等.水在有机质形成气态烃演化中作用的热模拟实验研究[J].自然科学进展,2006(10):1275-1281.
- [79]孙丽娜,张明峰,吴陈君,等.水对不同生烃模拟实验系统产物的影响[J].天然气地球科学,2015,26(3):524-532.
- [80]Mango F D,Elrod L W.The carbon isotope composition of catalytic gas:A comparative analysis with natural gas[J].Geochimica et Cosmochimica Acta,1999,63(7/8):1097-1106.
- [81]宁占武,王卫华,温美娟,等.过渡金属对有机质热解生烃过程的影响[J].天然气地球科学,2004(3):317-319.
- [82]祖小京,妥进才,张明峰,等.矿物在油气形成过程中的作用[J].沉积学报,2007(2):298-306.
- [83]王娟.咸化环境盐类物质与有机质相互作用研究[D].北京:中国石油大学,2009.
- [84]Ma Z L,Zheng L J,Xu X H,et al.Thermal simulation experiment of organic matter-rich shale and implication for organic pore formation and evolution[J].Petroleum Research,2017,2(4).
- [85]Wang F T,Guo S B.Influential factors and model of shale pore evolution:A case study of a continental shale from the Ordos Basin[J].Marine and Petroleum Geology,2019(102).
- [86]Esam A A E G,Mohamed F G,Mostafa M L,et al.Burial and thermal history simulation of the subsurface Paleozoic source rocks in Faghur basin,north Western Desert,Egypt:Implication for hydrocarbon generation and expulsion history[J].Egyptian Journal of Petroleum,2019,28(3).
- [87]Ma W J,Hou L H,Luo X,et al.Generation and expulsion process of the Chang 7 oil shale in the Ordos Basin based on temperature-based semi-open pyrolysis:Implications for in-situ conversion process[J].Journal of Petroleum Science and Engineering,2020(190).
- [88]Li J,Wang Y F,Ma W,et al.Evaluation on occluded hydrocarbon in deep-ultra deep ancient source rocks and its cracked gas resources[J].Natural Gas Industry B,2015,2(6).
- [89]孙丽娜,张明峰,吴陈君,等.油页岩生排烃模拟实验中不同液态烃产物特征[J].岩性油气藏,2017,29(6):23-31.
- [90]Zhang Y H,Wang Y F,Ma W,et al.Compositional Characterization of Expelled and Residual Oils in the Source Rocks from Oil Generation-Expulsion Thermal Simulation Experiments[J].ACS omega,2019,4(5).
- [91]Yu F N,Sun P C,Zhao K A,et al.Experimental constraints on the evolution of organic matter in oil shales during heating:Implications for enhanced in situ oil recovery from oil shales[J].Fuel,2020(261).
- [92]Tang X,Zhang J C,Jiang Z X,et al.Characteristics of solid residue,expelled and retained hydrocarbons of lacustrine marlstone based on semi-closed system hydrous pyrolysis:implications for tight oil exploration[J].Fuel,2015(162):186-193.
- [93]Franco N,Kalkreuth W,Perlba M D C R.Geochemical characterization of solid residues,bitumen and expelled oil based on steam pyrolysis experiments from Irati oil shale,Brazil:a preliminary study[J].Fuel,2010(89):1863-1871.
- [94]Bernard S,Horsfield B,Schulz H M,et al.Multi-Scale Detection of Organic and Inorganic Signatures Provides Insights into Gas Shale Properties and Evolution[J].Geochemistry,2010(70):119-133.
- [95]董大忠,程克明,王玉满,等.中国上扬子区下古生界页岩气形成条件及特征[J].石油与天然气地质,2010,31(3):288-299,308.
- [96]Cao Q,Zhou W,Deng H C,et al.Classification and controlling factors of organic pores in continental shale gas reservoirs based on laboratory experimental results[J].Journal of Natural Gas Science and Engineering,2015(27).
- [97]邹才能,董大忠,王社教,等.中国页岩气形成机理、地质特征及资源潜力[J].石油勘探与开发,2010,37(6):641-653.
- [98]熊亮.四川盆地及周缘下寒武统富有机质页岩孔隙发育特征[J].天然气地球科学,2019,30(9):1319-1331.
- [99]苗雅楠,李相方,王香增,等.页岩有机质热演化生烃成孔及其甲烷吸附机理研究进展[J].中国科学:物理学力学天文学,2017,47(11):41-51.
- [100]Miao S,Yu B,Zhang J,et al.Evolution of organic pores in marine shales undergoing thermocompression:a simulation experiment using hydrocarbon generation and expulsion[J].Journal of Natural Gas Science and Engineering,2018(59):406-413.
- [101]赵康安,孙平昌,于丰宁,等.民和盆地油页岩加热过程储集物性研究[J].新疆石油地质,2020,41(2):158-163.
- [102]吴松涛,朱如凯,崔京钢,等.鄂尔多斯盆地长7湖相泥页岩孔隙演化特征[J].石油勘探与开发,2015,42(2):167-176.
- [103]肖七林,刘安,李楚雄,等.高演化页岩纳米孔隙在过熟阶段的形成演化特征及主控因素:中扬子地区寒武系水井沱组页岩含水热模拟实验[J].地球科学,2020,45(6):2160-2171.
- [104]刘伟新,王延斌,秦建中.川北阿坝地区三叠系黏土矿物特征及地质意义[J].地质科学,2007(3):469-482.
- [105]Zhao W Z,Wang Z Y,He H Q,et al.Gas formation mechanism of marine carbonate source rocks in China[J].Science in China Press,2005,48(4).
- [106]戴方尧,郝芳,胡海燕,等.川东焦石坝五峰-龙马溪组页岩气赋存机理及其主控因素[J].地球科学,2017,42(7):1185-1194.
- [107]Clarkson C R,Solano N,Bustin R M,et al.Pore structure characterization of North American shale gas reservoirs using USANS/SANS,gasadsorption,and mercury intrusion[J].Fuel,2013(103).